Abstract: The framework for analyzing technology spillover effects are constructed on the basis of global industrial production network in this paper. We use panel data including 15 industries from 2002 to 2012 to measure the degree of technology spillover effects on labor productivity in global industrial production network by input-output tables. Evidences show that with the extent of industrial production networks embedded in global industrial production network become deeper, “structural blocking effect” exist in the process of industrial upgrading . The impact of factors is more important than technical progress transition path way to achieve transition to regional emerging industries in global industrial production networks . You need to pay more attention to invest in large-scale equipment and R & D investment. In view of this situation, the author proposes a global view, taking strategy about upgrade between the chains and "in the global production network, not in the global production networks" to break structural blocking effect, to stimulate different types of subjects continued innovation of endogenous power. Enhancing their own division of labor status by the various levels of innovation ,grasping the development of the initiative and trying to climb the value chain of high value-added sectors. Finally realizing the Chinese industrial upgrading, and improving the international competitiveness.