Abstract: Technological progress is an important factor for reducing energy consumption and CO2 emission, and the driving force for promoting China's industrial green low-carbon transformation. Based on the consideration of energy consumption and emission factors, we deduce the theoretical mechanism of technological progress to promote energy saving and emission reduction through mathematical equations, and use the non-parameter SML model to calculate and decompose the technological progress of green growth in China's 35 industries from 1994 to 2014. According to the high energy consumption and emission group, we use the panel model to make regression on energy consumption intensity and CO2 emissions intensity respectively, and explores the performance of different types of technological progress to reduce energy consumption and CO2 emission reduction. The results show that the technological innovation is the main driving force to promote the industry's green total factor productivity in China. The energy-saving and consumption-reducing performance of cutting-edge technology innovation is the highest. The pure technology efficiency of CO2 emission reduction is the highest. Technological progress to promote energy saving and CO2 emission reduction effect there is asymmetry, technology Progress of CO2 emission reduction performance is greater than energy saving. Energy consumption structure adjustment of CO2 emission reduction performance is greater than energy saving, explained the existence of "high energy consumption and low emission industry , high emission and low energy industry" mystery.