Abstract: In the context of economic transformation, innovation and entrepreneurship have become new engines driving China's economic development. The reasonable allocation of opportunities and resources in the entrepreneurial process will determine the entrepreneurial performance of enterprises. However, how to complete the mutual utilization of entrepreneurial opportunities and resources is still an unsolved problem. From entrepreneurial opportunities resources integration perspective, we selected China FAW Group Corporation as the research object, take the network as a situational variables to explore opportunities and resources under the impetus of the business leaders, how to symbiotic evolution and promote innovation diffusion mechanism then draw the following conclusions: (1) the interaction of entrepreneurial opportunities and resources is found in a dual dynamic behavior of the network level. (2) network expansion and clustering are system-driven integration behaviors, which jointly promote innovation diffusion and entrepreneurship strategy update. (3) according to the organizational development stage, leaders should realize the advantage allocation of opportunities, resources and innovation to maintain the dynamic balance of interactive flow within the entrepreneurial control system.