Abstract: Based on the innovation capability structure perspective, the study deconstructs the enterprises’ boundary-spanning search (BSS) from the organization-technology dimension, and analyzes their different influence on the organizational ambidexterity capability (OAC). The main results are shown as following: First, the BSS behavior can be divided into organizational and technological boundary spanning, which can be further divided into technology-driven and market-driven BSS, generic technology-oriented and product technology-oriented BSS. Secondly, the different dimensions have variant influences on OAC. Technology-driven and generic technology-oriented BSS have positive influences on exploratory capability, while market-driven, generic technology-oriented and product technology-oriented BSS have positive influence on exploitative capability. Thirdly, the research breaks through the theoretical assumption in March (1991) and finds that the OAC is not absolutely exclusive; the exploratory capability has significant positive impact on exploitative capability. The conclusions expand the perspective and dimension of organization search theory, which enrich the empirical studies about organizational ambidexterity in the context of emerging economy.