Abstract: The rapid development of technology and governance is the only way to achieve sustainable development to meet the need of energy, the environment and the challenges of climate change; however, technology governance is short of a clear conceptual framework. Based on the theory of collaborative governance and the technology research framework of "structure - process - relationship" , this framework implies the rear situation of “rear” factors, especially under the background of China, rear value brings about the impact and distortion to the technology policy implementation. Therefore, this paper puts forward "value - structure - process - relationship" technology collaborative governance framework and mechanism to explain how to adjust and shape the control technology form between the structure of collaborative governance body and the role and relationship of multiple subjects participate in the governance network in order to improve the acceptable degree of technology policy. The study results suggest that technology collaborative governance framework shall include scientific and technological personnel, association for science and technology, government, enterprises, colleges and universities, the financial sector, mediation and other social organizations and the public, and foreign department eight main body; Technical collaborative governance mechanism shall include accountability, participation mechanism, evaluation mechanism, communication mechanism and sharing mechanism. Research results suggest technical framework of collaborative governance and mechanism can apply and replicate the similar government governance issues to provide reference and experience for like ecological environment of collaborative governance, urbanization coordinated management of our country.